The configuration of atoms in a molecule determines the strength of the forces (bonds or intermolecular forces) between the particles and therefore the physical properties (e.g., melting point, boiling point, solubility, vapor pressure) of a material. For a given substance, the average kinetic energy (and therefore the temperature) needed for a change of state to occur depends upon the strength of the intermolecular forces between the particles. Therefore, the melting point and boiling point depend upon the amount of energy that is needed to overcome the attractions between the particles. Substances that have strong intermolecular forces or are made up of three- dimensional networks of ionic or covalent bonds tend to be solids at room temperature and have high melting and boiling points. Nonpolar organic molecules are held together by weak London dispersion forces. However, substances with longer chains provide more opportunities for these attractions and tend to have higher melting and boiling points. Increased branching of organic molecules interferes with the intermolecular attractions that lead to lower melting and boiling points.
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